
Charts & Tables Definitions
Absolute Zero The lowest temperature attainable. All
molecular activity is considered to cease. Its value is -459.67°F
(-273.15°C).
Absorption The penetration of matter in bulk into other
matter, as in the dissolving of a gas in liquid.
Adsorption The surface retention of solid, liquid, or
gas molecules, atoms, or ions by a solid or liquid.
Boiling Point The temperature of a liquid at which the
vapor pressure equals the surrounding pressure (normally specified
at 1 atm.).
British Thermal Unit The quantity of heat required to
raise the temperature of 1 pound of water 1°F.
Calorie The quantity of heat required to raise the temperature
of 1 gram of water 1°C.
Catalyst A substance that initiates a chemical reaction
and allows it to proceed under different conditions than otherwise
possible.
Coefficient of Viscosity A measure of the tendency of
a fluid to resist shear. The unit for viscosity is the poise, which
is defined as the resistance (in dynes per square centimeter of
its surface) of one layer of fluid to the motion of a parallel layer
one centimeter away and with a relative velocity of one centimeter
per second.
Critical Pressure The pressure under which a substance
may exist as a gas in equilibrium with the liquid at critical temperature.
Critical Temperature The temperature above which a gas
cannot be liquefied by pressure alone.
Cryogenic Fluid A gas that liquefies at very low temperatures
(from -459.67°F absolute zero to approximately -200°F).
Density The weight of a substance per unit of volume.
Dew Point The temperature at which liquid first condenses.
Diameter Index Safety System (DISS) DISS outlet valves
are generally used with high-purity products, toxics, and corrosives.
Valves equipped with DISS outlet assignment provide a metal-to-metal
seal that creates low particles, a permeation-free environment,
and good leak integrity.
Dielectric Constant The specific inductive capacitance
of a material. It is equal to the ratio of the capacitances of two
condensers of identical size, one using the particular dielectric,
the other using air or a vacuum as the dielectric.
Eductor Tube An eductor tube or dip tube permits the
withdrawal of liquefied compressed gases in the liquid phase with
the cylinder in the normal upright position, without having to invert
the cylinder. Air Products offers two types of eductor tubes: gooseneck
tubes and full-length tubes.
Expansion Engine An apparatus for extracting work from
a gas by allowing the gas to expand between two pressure levels.
As the energy is extracted, the gas temperature is lowered.
Expansion Valve A valve through which a fluid may be
expanded from one pressure to a lower pressure at a controlled rate.
Flammable Limits The concentration of flammable vapor
in air, oxygen, or other oxidants that will propagate flame upon
contact when provided with a source of ignition. The lower explosive
limit (LEL) is the concentration below which a flame will not propagate;
the upper explosive limit (UEL) is the concentration above which
a flame will not propagate. A change in temperature or pressure
may vary the flammable limits.
Fractional Distillation A process used to separate the
constituents of a liquid mixture due to differences in boiling points
of the constituents.
Joule-Thomson Effect The change in temperature resulting
from expansion of a gas or vapor through an orifice or other restriction.
Kinetic Theory of Gases Gases are considered to be made
up of minute, perfectly elastic particles which are moving at random
with high velocities, colliding with each other and with the walls
of the containing vessel. The pressure exerted by a gas is due to
the combined effect of the impacts of the moving molecules upon
the walls of the containing vessel. The magnitude of the pressure
is dependent upon the kinetic energy of the molecules and their
number.
Latent Heat of Fusion The heat required to convert a
unit mass of a substance from a solid to the liquid state at the
same temperature and pressure.
Latent Heat of Sublimation The heat required to convert
a unit mass of substance from the solid state to the gaseous state.
Latent Heat of Vaporization The heat required to convert
a unit mass of substance from the liquid state to the gaseous state
at a given pressure (and temperature).
Molecular Weight The average mass of a molecule calculated
as the sum of the atomic weights of the constituent atoms.
Normal Boiling Point The temperature at which a liquid
boils when under a total pressure of one atmosphere.
Normal Sublimation Temperature The temperature at which
a solid sublimes under a total pressure of one atmosphere.
Pyrophoric Gas A gas that can spontaneously self-ignite
when exposed to normal atmospheric conditions.
Restrictive Flow Orifice (RFO) A safety device placed
in the outlet of a cylinder valve that is intended to limit the
release rate of a hazardous gas to a maximum specified range in
the event of the inadvertent opening of the valve, or failure of
the system downstream of the valve outlet.
Specific Gravity The ratio of weight of a substance at
a given temperature to the weight of the same volume of another
substance at a given temperature. For liquids, the comparison is
to water; for gases, the comparison is to air.
Specific Heat The ratio of the heat capacity of a body
to the heat capacity of water at some reference temperature.
Specific Heat Ratio Ratio of specific heat at constant
pressure to the specific heat at constant volume at a particular
temperature.
Specific Volume The volume occupied by one unit mass
of substance.
Superconductivity The phenomenon by which some substances
suddenly lose all electrical resistance when their temperature is
reduced. These transitions occur at temperatures lower than that
of liquid hydrogen.
Thermal Conductivity The property of a material which
describes the rate at which heat will be conducted through a unit
area of material for a given driving force. It is dependent on the
material and upon its temperature.
Triple Point The temperature and pressure at which the
solid, liquid, and vapor phases of a substance are in equilibrium
with one another.
Vapor Pressure The pressure exerted when a solid or liquid
is in equilibrium with its own vapor. Vapor pressure is a function
of the substance and the temperature.
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